Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 30, Pages 4254-4257Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc00295e
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Funding
- Singapore National Research Foundation under its Environment & Water Research Programme [1301-IRIS-49]
- Singapore Economic Development Board
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Two-dimensional (2-D) CuBDC nanosheets (ns-CuBDC) with high-aspect-ratios were deliberately paired with polymers possessing high free volumes to fabricate high performance gas separation membranes. Owing to the molecular sieving effect of the filler, a small ns-CuBDC loading (2-4 wt%) could significantly improve the CO2/CH4 selectivities of membranes, resulting in performances that surpass the upper bound limit for polymer membranes.
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