Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 25, Pages 3547-3550Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc00214a
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Funding
- Agence Nationale de la Recherche (PET-Cat'') [ANR-13-BS07-0006-01]
- University of Bordeaux
- CNRS
- Region Aquitaine
- Agence Nationale de la Recherche (ANR) [ANR-13-BS07-0006] Funding Source: Agence Nationale de la Recherche (ANR)
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A light-promoted methodology for the iodotrifluoromethylation of alkenes was developed. For the first time a Togni reagent was exploited as the source of both the CF3 group and iodine atom. Preliminary mechanistic studies suggest that both CF3I and 2-iodobenzoic acid are direct sources of the iodine atom that is transferred to the products.
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