Journal
DALTON TRANSACTIONS
Volume 46, Issue 14, Pages 4589-4594Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7dt00614d
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Funding
- National Natural Science Foundation of China [21371092, 21601045]
- National Basic Research Program of China [2010CB923303]
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A pair of new enantiomeric Zn(II) complexes with 5-fold interpenetrating diamondoid frameworks have been synthesized using two achiral tritopic and V-shaped ligands through spontaneous resolution, which crystallize in orthorhombic crystal systems with chiral P2(1)2(1)2(1) space groups, showing a strong second harmonic generation response. In the presence of enantiopure propane-1,2-diol as a chiral inducing agent, they are driven to controllable homochiral crystallization of the desired enantiomorph, confirmed by single crystal X-ray diffraction and circular dichroism spectroscopy.
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