Journal
CARBOHYDRATE POLYMERS
Volume 162, Issue -, Pages 71-81Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.carbpol.2017.01.049
Keywords
Cellulose; Pectin; Mechanics; XRD; SANS; SAXS
Categories
Funding
- Australian Research Council (ARC) [CE110001007]
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Plant cell walls have a unique combination of strength and flexibility however, further investigations are required to understand how those properties arise from the assembly of the relevant biopolymers. Recent studies indicate that Ca2+-pectates can act as load-bearing components in cell walls. To investigate this proposed role of pectins, bioinspired wall models were synthesised based on bacterial cellulose containing pectin-calcium gels by varying the order of assembly of cellulose/pectin networks, pectin degree of methylesterification and calcium concentration. Hydrogels in which pectin-calcium assembly occurred prior to cellulose synthesis showed evidence for direct cellulose/pectin interactions from small angle scattering (SAXS and SANS), had the densest networks and the lowest normal stress. The strength of the pectin-calcium gel affected cellulose structure, crystallinity and material properties. The results highlight the importance of the order of assembly on the properties of cellulose composite networks and support the role of pectin in the mechanics of cell walls. (C) 2017 Elsevier Ltd. All rights reserved.
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