4.7 Article

The synthesis of B, N-carbon dots by a combustion method and the application of fluorescence detection for Cu2+

Journal

CHINESE CHEMICAL LETTERS
Volume 28, Issue 5, Pages 1119-1124

Publisher

ELSEVIER SCIENCE INC
DOI: 10.1016/j.cclet.2016.12.009

Keywords

Combustion method; B, N-carbon dots; Fluorescence method; Cu2+; Static fluorescence quenching

Funding

  1. National Natural Science Foundation of China [21375112]
  2. Marine high-tech industry development projects of Fujian Province [2015-19]

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Heteroatom doping is an efficient approach to regulate the fluorescence properties of carbon dots. Using aminophenylboronic acid as the raw material, a combustion method was developed for the synthesis of boron, nitrogen-doped carbon dots (B, N-carbon dots). The B, N-carbon dots emitted green fluorescence and displayed high resistance to both photo bleaching and ionic strength. A facile fluorescence sensing approach for Cu2+ was fabricated via static fluorescence quenching. Under optimal conditions, a rapid detection of Cu2+ could be completed in 2 min with a linearity ranging from 1 mu mol/L to 25 and a detection limit of 0.3 pt mu mol/L. Furthermore, the proposed method showed potential applications for the detection of Cu2+ in natural water samples. (C) 2016 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.

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