Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 56, Issue 19, Pages 5341-5344Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201701231
Keywords
amides; arylation; C-C activation; reaction mechanisms; ruthenium
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Funding
- European Research Council under the European Community [307535]
- Chinese Scholarship Council
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Ruthenium(II)biscarboxylate catalysis enabled selective C-C functionalizations by means of decarbamoylative C-C arylations. The versatility of the ruthenium(II) catalysis was reflected by widely applicable C-C arylations and C-C alkylations of aryl amides, as well as acids with modifiable pyrazoles, through facile organometallic C-C activation.
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