Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 27, Pages 3870-3873Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc01636k
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Funding
- National Basic Research Program of China [2015CB931900, 2012CBA01200]
- National Natural Science Foundation [21421002, 21472222, 21502214, 21672242]
- Chinese Academy of Sciences [XDA02020105, XDA02020106]
- Science and Technology Commission of Shanghai Municipality [15DZ1200102, 14ZR1448800]
- Syngenta PhD Fellowship
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Difluoroethylsulfonium salt, Ph2S+CH2CF2H OTf-, was developed into a convenient difluoromethylcarbene reagent for the iron-catalyzed cyclopropanation of terminal olefins, giving various difluoromethyl-cyclopropanes with excellent diastereoselectivities and in high yields.
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