4.7 Article

Diamondoid-structured polymolybdate-based metal-organic frameworks as high-capacity anodes for lithium-ion batteries

Journal

CHEMICAL COMMUNICATIONS
Volume 53, Issue 37, Pages 5204-5207

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc10208e

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Funding

  1. National Natural Science Foundation of China [21622104, 21371099, 21471080]
  2. NSF of Jiangsu Province of China [BK20141445]
  3. Priority Academic Program Development of Jiangsu Higher Education Institution
  4. Foundation of Jiangsu Collaborative Innovation Center of Biomedical Functional Materials

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Two novel isostructural polyoxometalate (POM)-based metalorganic frameworks (MOFs) with diamond topology, NENU-506 and NENU-507, were hydrothermally synthesized. They not only combine the advantages of both POMs and MOFs, but also show excellent chemical and thermal stability. Notably, NENU-507 exhibited a high reversible capacity of 640 mA h g(-1) after 100 cycles when applied as an anode material in lithium-ion batteries.

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