4.7 Article

Solvent-free on-surface synthesis of boroxine COF monolayers

Journal

CHEMICAL COMMUNICATIONS
Volume 53, Issue 37, Pages 5147-5150

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc01131h

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Funding

  1. Deutsche Forschungsgemeinschaft DFG [LA1842/4-1]
  2. Nanosystems-Initiative-Munich excellence cluster

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A protocol is proposed for the solvent-free on-surface synthesis of covalent organic framework monolayers by condensation of diboronic acids. Monomers are vapor-deposited and water is used for equilibrium regulation. Samples are characterized on progressively smaller length scales by light microscopy, Scanning Electron Microscopy, and Scanning Tunneling Microscopy.

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