4.7 Article

Built-in TTF-TCNQ charge-transfer salts in π-stacked pillared layer frameworks

Journal

CRYSTENGCOMM
Volume 19, Issue 17, Pages 2300-2304

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ce00492c

Keywords

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Funding

  1. MEXT of Japan [15H00983]
  2. E-IMR project
  3. Iketani Science and Technology Foundation
  4. Support Program for Interdisciplinary Research
  5. [16H02269]
  6. [15K13652]
  7. [26810029]
  8. Grants-in-Aid for Scientific Research [16H02269, 26810029, 17H05137, 15H00983] Funding Source: KAKEN

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A TTF-TCNQ charge-transfer salt was incorporated in a layer structure with paddlewheel-type carboxylate-bridged dirhodium(II, II) complexes ([Rh-2]) to construct pi-stacked pillared layer frameworks of formula (TTF)(n)[{Rh}(2)(TCNQ)] (n = 1 or 2).

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