Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 56, Issue 20, Pages 5556-5560Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201702142
Keywords
hydrogenation; imines; ligand effects; ruthenium; synthetic methods
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Funding
- DST-SERB [EMR/2016/003002]
- IISER Bhopal
- UGC
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Disclosed here is a molecular switch which responds to acid-base stimuli and serves as a bi-state catalyst for two different reactions. The two states of the switch serve as a highly active and poorly active catalyst for two catalytic reactions (namely a hydrogenation and a dehydrogenative coupling) but in a complementary manner. The system was used in an assisted tandem catalysis set-up involving dehydrogenative coupling of an amine and then hydrogenation of the resulting imine product by switching between the respective states of the catalyst.
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