Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 23, Issue 20, Pages 4770-4773Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201700668
Keywords
dual-emissive; iridium; N-heterocyclic carbenes; ratiometric O-2 probes; terpyridine
Categories
Funding
- DST-SERB [EMR/2016/003002]
- IISER Bhopal
- CSIR
- DST-INSPIRE
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A new class of bi-luminophoric dyad has been designed, consisting of an oxygen-sensitive phosphorescent NHC-Ir-III center with a remotely integrated oxygen-insensitive fluorescent terpyridine unit. The new terpyridine flurophore-integrated NHC-Ir-III molecule was demonstrated as a potential ratiometric O-2 probe with built-in internal reference, exhibiting tunable dual-emissive features, as well as highly linear and reversible O-2-response behavior.
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