Journal
CATALYSIS COMMUNICATIONS
Volume 95, Issue -, Pages 12-15Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.catcom.2017.02.027
Keywords
Organo catalysis; Proline; Enantioselectivity reversal; Aldol reaction; MIL-101; Chiral MOFs
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Proline-functionalized H2N-MIL-101(Al) was synthesized from L- or p-proline-terephthalic acid and used in the catalytic aldol reaction of p-nitrobenzaldehyde with acetone to achieve up to 95% conversion and an ee-value of 29% but in a reversal in enantioselectivity compared to the reaction under homogeneous L- or D-proline organocatalytic condition. (C) 2017 Elsevier B.V. All rights reserved.
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