Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 38, Pages 5279-5282Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc01861d
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Funding
- NSFC [21472050, 21272075]
- DFMEC [20130076110023]
- Fok Ying Tung Education Foundation [141011]
- Program for Shanghai Rising Star [15QA1401800]
- Professor of Special Appointment (Eastern Scholar) at Shanghai Institutions of Higher Learning
- National Program
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A chemo-and regio-selectively controllable approach for construction of diverse benzo-heterocycles is established. A new strategy for using the ligand effect in gold catalysis to control the regioselectivity in the cyclization of o-alkynyl-N-methoxyl-benzamide is successfully achieved. Meanwhile, the chemoselectivity between nitrogen and oxygen nucleo-philes is precisely switched by gold and platinum catalysts.
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