Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 23, Issue 27, Pages 6527-6530Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201701346
Keywords
decatungstate anion; hydrogen transfer; photocatalysis; radical reactions; vinylpyridines
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Funding
- MIUR [RBSI145Y9R]
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The photocatalyzed addition of several hydrogen donors (ethers, aldehydes, alkanes, amides) onto vinylpyridines was achieved. This approach provided access to alkylpyridines, which are important building blocks for the preparation of compounds with biological activity. The strategy was very simple and straightforward because it required only a small amount of a cheap decatungstate salt as photocatalyst. As an added advantage, the reaction could be performed under sunlight irradiation as well as under flow conditions.
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