Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 56, Issue 21, Pages 5825-5828Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201702406
Keywords
enantioselective catalysis; ester hydrogenation; ferrocene; manganese; reduction
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Funding
- EPSRC
- Engineering and Physical Sciences Research Council [1398296, 1654521] Funding Source: researchfish
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Anew hydrogenation catalyst based onamanganese complex of a chiral P,N,N ligand has been found to be especially active for the hydrogenation of esters down to 0.1 mol% catalyst loading, and gives up to 97% ee in the hydrogenation of pro-chiral deactivated ketones at 30-50 degrees C.
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