Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 33, Pages 4612-4615Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc01228d
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Funding
- Wuhan University [203273463, 203600400006]
- Important Sci-Tech Innovative Project of Hubei Province [2015ACA058]
- National Natural Science Foundation of China [21372179, 21432007, 21502145]
- Natural Science Foundation of Hubei Province [2016CFB449]
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Cobalt-catalyzed highly (Z)-selective semihydrogenation of alkynes using molecular H-2 was developed using commercially available and cheap cobalt precursors. A variety of (Z)-alkenes were obtained in moderate to excellent selectivities [( Z)-alkene/(E)-alkene/alkane ratio up to >99 : 1 : 1] and it was found that the readily available ethylenediamine ligand is crucial in determining the selectivity.
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