Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 33, Pages 4562-4564Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc02311a
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Funding
- Science and Engineering Research Board (SERB), India
- Ramanujan research grant [SB/S1/RJN-073/2014]
- [SB/S1/IC-10/2014]
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A benz-amidinato calcium compound, [PhC(NiPr)(2)Cal] (1), catalyzed hydroboration of a wide range of aldehydes and ketones using pinacolborane (HBpin) at room temperature is reported. The catalyst shows functional group tolerance even towards OH and NH groups. The strategy was further extended to imines.
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