Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 23, Issue 23, Pages 5410-5413Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201605218
Keywords
amines; borrowing hydrogen; manganese; methylation; pincer complex
Categories
Funding
- 'Region Bretagne'
- LIKAT
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A novel lutidine-based manganese PNP-pincer complex has been synthesized for the selective N-methylation of aromatic amines with methanol. Using borrowing hydrogen methodology, a selection of differently functionalized aniline derivatives is selectively methylated in good yields.
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