Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 30, Pages 4238-4241Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc00425g
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Funding
- National Nature Science Foundation of China [91622102, 21471011]
- High-Caliber Talents Project of Beijing Municipal Institution
- BSRF
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A bifunctional ligand H2L featuring primary (pyrazole) and secondary (acetylacetone) coordination sites was preferentially reacted with dimetallic [M-2(NO3)(2)](NO3)(2) linkers at the pyrazolyl end of H2L, giving rise to dimetallic corners. Subsequently, the corners serve as the secondary site with M' to form water-soluble organo-heterometallic [M12M'L-4(12)] cages in a stepwise mode.
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