4.7 Article

Extraction of minor actinides, lanthanides and other fission products by silica-immobilized BTBP/BTPhen ligands

Journal

CHEMICAL COMMUNICATIONS
Volume 53, Issue 28, Pages 4010-4013

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc01286a

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Funding

  1. UK Engineering and Physical Sciences Research Council [EP/M026485/1]
  2. Grant Agency of the Czech Technical University in Prague [SGS15/216/OHK4/3T/14]
  3. EPSRC [EP/M026485/1] Funding Source: UKRI
  4. Engineering and Physical Sciences Research Council [EP/M026485/1] Funding Source: researchfish

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Novel BTBP [bis-(1,2,4-triazin-3-yl)-2,2'-bipyridine]/BTPhen [bis-(1,2,4-triazin-3-yl)-1,10-phenanthroline] functionalized silica gels have been developed to extract minor actinides, lanthanides and other fission products. BTPhen functionalized silica gel is capable of near-quantitative removal of Am(III) in the presence of Eu(III) from aqueous HNO3, while BTBP functionalized silica gel is able to remove problematic corrosion and fission products that are found in PUREX raffinates.

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