3.8 Article

Crystal structure of 1,3-bis[(E)-benzylideneamino]propan-2-ol

Publisher

INT UNION CRYSTALLOGRAPHY
DOI: 10.1107/S2056989017004741

Keywords

crystal structure; hydrogen bonding; C-H center dot center dot center dot pi interactions; Schiff bases

Funding

  1. Direccion de Investigaciones, Sede Bogota (DIB) de la Universidad Nacional de Colombia [35816]

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In the title compound, C17H18N2O, the central carbon atom with the OH substituent and one of the (E)-benzylideneamino substituents are disordered over two sets of sites with occupancies of 0.851 (4) and 0.149 (4). The relative positions of the two disorder components is equivalent to a rotation of approximately 60 degrees about the C-N single bond. In the crystal, the molecules are held together by O-H center dot center dot center dot N hydrogen bonds, forming simple C(5) chains along the b-axis direction. In addition, pairs of the chains are further aggregated by weak C-H center dot center dot center dot pi interactions.

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