Journal
CHEMCATCHEM
Volume 9, Issue 10, Pages 1788-1793Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201700004
Keywords
boron; dehydrogenation; hydrocarbons; hydroxylation; nitrides
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Funding
- National Natural Science Foundation of China [21225312, U1462120, 21473206, 21373035]
- Cheung Kong Scholars Program of China [T2015036]
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Oxidative dehydrogenation of propane to olefins is a promising alternative route to industrialized direct dehydrogenation, but encounters the difficulty in selectivity control for olefins because of the overoxidation reactions that produce a substantial amount of undesired CO2. Here we report edge-hydroxylated boron nitride, a metal-free catalyst, that efficiently catalyzed dehydrogenation of propane to propylene with superior selectivity (80.2 %) but with only negligible CO2 formation (0.5%) at a given propane conversion of 20.6 %. Remarkable stability was evidenced by the operation of a 300 h test with steady conversion and product selectivity. The active BNO center dot site, generated dynamically through hydrogen abstraction of B-OH groups by molecular oxygen, triggered propane dehydrogenation by selectively breaking the C-H bond but simultaneously shut off the pathway of propylene overoxidation towards CO2.
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