Journal
APPLIED CATALYSIS B-ENVIRONMENTAL
Volume 210, Issue -, Pages 116-120Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apcatb.2017.03.046
Keywords
Acetylene hydrochlorination; Metal free; Carbon catalysis; Carbon deposit; Catalyst regeneration
Funding
- National Natural Science Foundation of China [21425312, 21321002, 21373207]
Ask authors/readers for more resources
Acetylene hydrochlorination is an important coal-based technology for production of vinyl chloride, the monomer of one of the world mostly used plastics. Despite of the great potentials demonstrated for carbon-based catalysts to replace the toxic mercury chloride, the stability and the deactivation mechanism are rarely discussed, which is essential for real applications. Herein, we present a detailed study on the deactivation mechanism of nitrogen doped carbon based catalyst in acetylene hydrochlorination. The results show that the deactivation was likely caused by the carbon-like deposition over the catalyst, which can be regenerated with high temperature NH3 treatment. (C) 2017 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available