Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 23, Issue 25, Pages 5953-5956Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201605514
Keywords
carbenes; C-H activation; cyclopropanation; cyclopropane; iminoboranes
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Funding
- Deutsche Forschungsgemeinschaft
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A remarkably mild, catalyst-free cyclopropanation reaction is confirmed by low-temperature isolation of a fused bicyclic cyclopropane intermediate. This intermediate is one of two that were isolated and fully characterised in a three-step temperature-controllable reaction cascade.
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