Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 42, Pages 5733-5736Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc02244a
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- Centre for Chemical and Materials Analysis in the School of Chemistry at University of Birmingham (UoB)
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Alkynyl sulfoxides are shown to act as alpha-sulfinyl metallocarbene synthons under oxidative gold catalysis, enabling reactions that are not available from diazo-precursors. This strategy is exemplified in the synthesis of fused alpha-sulfinyl cyclopropanes.
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