Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 56, Issue 22, Pages 6088-6092Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201700239
Keywords
nitrogen; photochemistry; protonation; RIXS (resonant inelastic X-ray scattering); selective bond cleavage
Categories
Funding
- ERC-ADG under the Horizon 2020 EU Framework Programme for Research and Innovation [669531/EDAX]
- Helmholtz Virtual Institute [VI 419]
- Swedish Research Council (VR)
- Carl Trygger Foundation
- Volkswagen-Stiftung
- Office of Basic Energy Sciences of the US Department of Energy [DE-SC0002190]
- US Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-76SF00515]
- LCLS
- Stanford University through the Stanford Institute for Materials and Energy Sciences (SIMES)
- Lawrence Berkeley National Laboratory (LBNL)
- University of Hamburg through the BMBF priority program [FSP 301]
- Center for Free Electron Laser Science (CFEL)
- DOE Office of Basic Energy Sciences
Ask authors/readers for more resources
The femtosecond excited-state dynamics following resonant photoexcitation enable the selective deformation of N-H and N-C chemical bonds in 2-thiopyridone in aqueous solution with optical or X-ray pulses. In combination with multiconfigurational quantum-chemical calculations, the orbital-specific electronic structure and its ultrafast dynamics accessed with resonant inelastic X-ray scattering at the N 1s level using synchrotron radiation and the soft X-ray free-electron laser LCLS provide direct evidence for this controlled photoinduced molecular deformation and its ultrashort time-scale.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
