Journal
COORDINATION CHEMISTRY REVIEWS
Volume 340, Issue -, Pages 247-265Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2017.02.011
Keywords
Lanthanoids; Lanthanoid(II); Lanthanoid(III); Lanthanoid(IV); Formamidinates
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Funding
- Australian Research Council [DP160101640]
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This comprehensive review covers the progress of rare earth chemistry with formamidinate ligands to date. The ligands involved offer varying steric and electronic effects and focus on the N, N'-bis(aryl) forma midinates. Synthetic pathways to divalent, trivalent and tetravalent complexes, their structural aspects, reactivity and potential applications in catalysis are extensively discussed. (C) 2017 Elsevier B.V. All rights reserved.
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