Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 56, Issue 23, Pages 6435-6439Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201700282
Keywords
alkynes; gold; heterogeneous catalysis; hydrochlorination; vinyl chlorides
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Funding
- ITQ
- Severo Ochoa program
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HCl in solution accepts electron density from Au NPs and partially reduces at room temperature, as occurs with other simple diatomic molecules, such as O-2 and H-2. The activation can be run catalytically in the presence of alkynes to give exclusively E-vinyl chlorides, after the regio-and stereoselective transfer of HCl. Based also on this method, vinyl chloride monomer (VCM) can be produced in a milder and greener way than current industrial processes.
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