Journal
CHINESE JOURNAL OF CHEMICAL ENGINEERING
Volume 25, Issue 5, Pages 595-601Publisher
CHEMICAL INDUSTRY PRESS CO LTD
DOI: 10.1016/j.cjche.2016.10.012
Keywords
ZIF-7; Metal-organic framework; Size distribution; Adsorption; CO2 capture; Gas
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Reliable estimation of the pore size distribution (PSD) in porous materials such as metal-organic frameworks (MOFs) and zeolitic imidazolate frameworks (ZIFs) is crucial for accurately assessing adsorption capacity and corresponding selectivity. In this study, the so-called zeolitic imidazolate framework-7 (ZIF-7) is successfully synthesized via relatively fast and convenient microwave technique. The morphology and structure of the obtained MOF were characterized by XRD, SEM and N-2 and CO2 adsorption/desorption isotherms at 77 K and 0 C respectively. Then, to determine the PSD of the fabricatedMOF, carbon dioxide isotherms are experimentally measured at various temperatures up to atmospheric pressure. Afterward, the experimental CO2 isotherms data are utilized in two recently proposed in-house algorithms of SHN1 and SHN2 to extract the true PSD of manufactured ZIF-7. The obtained results revealed that median pore diameter of the fabricated ZIF-7 is estimated around 0.404 nmand 0.370 nmby using CO2 isotherms at 273 K and 298 K respectively. These values are in good agreement with the real pore diameter of 0.42 nm. Moreover, experimental data of water adsorption isotherms over four different MOFs, borrowed from literature, are employed to illustrate further effectiveness of the above algorithms on successful determination of the corresponding pore size distributions. All predicted PSDs are proved to be in good agreementwith those obtained fromindependentmethods such as topology andmorphology studies. (C) 2016 The Chemical Industry and Engineering Society of China, and Chemical Industry Press. All rights reserved.
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