Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 56, Issue 23, Pages 6558-6562Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201702857
Keywords
carbon dioxide; cross-coupling; nickel; regioselectivity; synthetic methods
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Funding
- ICIQ
- European Research Council [ERC-277883]
- MINECO (Severo Ochoa Excellence Accreditation) [SEV-2013-0319, CTQ2015-65496-R]
- Cellex Foundation
- Alexander von Humboldt Foundation
- MINECO
- ICREA Funding Source: Custom
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A switchable site-selective catalytic carboxylation of allylic alcohols has been developed in which CO2 is used with dual roles, both facilitating C-OH cleavage and as a C-1 source. This protocol is characterized by its mild reaction conditions, absence of stoichiometric amounts of organometallic reagents, broad scope, and exquisite regiodivergency which can be modulated by the type of ligand employed.
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