Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 40, Pages 5515-5518Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc02704d
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Funding
- National Natural Science Foundation of China [21373142, 21401134, 21531006]
- State Key Laboratory of Organometallic Chemistry of Shanghai Institute of Organic Chemistry [2015kf-07]
- SooChow Scholar Program of Soochow University
- Science and Technology Department of Jiangsu Province [BK20140307]
- Department of Education of Jiangsu Province [14KJB150023]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
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A protonated mononuclear complex [Zn(Hbpvp) Cl-3] (1) is assembled by solvothermal reaction of Zn(NO3)(2)center dot 6H(2)O with 3,5-bis-(2-(pyridin-4-yl) vinyl) pyridine (bpvp) in DMF/H(2)Owith a few drops of concentrated HCl added. Hydrogen-bonded zigzag chains of 1 crystallize over time to form large-size hollow hexagonal tubular crystals whose evolution from irregular crystal seeds is monitored by SEM and PXRD. Upon UV light irradiation, single crystals of 1 undergo a stereoselective [2+2] photocycloaddition while its Methyl Blue-coated crystals keep intact.
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