Journal
CHEMISTRY-AN ASIAN JOURNAL
Volume 12, Issue 9, Pages 978-981Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201700239
Keywords
alkylation; allylic substitution; C-C bond cleavage; copper; radicals
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Funding
- program to disseminate tenure tracking system, MEXT, Japan
- Sasakawa Scientific Research Grant from Japan Science Society
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Although numerous reports exist on strained C-C bond cleavage reactions in aryl substitutions, the cleavage methodology for unstrained C-C bonds in alkylation reactions has not yet been established. We found that unstrained allylic C-C bonds can be cleaved using -radicals to form C(sp(3))-C(sp(3)) bonds in the presence of a copper catalyst. In this reaction, the property of leaving and loading radicals is very important for radical fragmentations. In this paper, we investigated the effects of these properties in cleavage reactions for unstrained C-C bonds.
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