Journal
CHEMICAL PHYSICS
Volume 490, Issue -, Pages 1-6Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.chemphys.2017.03.010
Keywords
ZnO nanorods; Poly(3-hexylthiophene); Incident photon to electron conversion efficiency (IPCE); Photoelectrochemical cell; Photoconversion efficiency; Photosensing
Funding
- CSIR Extramural Research Scheme, Government of India [03(1316)/14/EMR-II]
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Photoelectrochemical properties of ZnO nanorods (ZnO NRs) and poly(3-hexylthiophene) (P3HT) polymer hybrid photoanodes have been studied. The hybrid photoanodes demonstrated higher photoconversion efficiency, incident photon to current conversion efficiency (IPCE) and lower interfacial resistance compared to pristine ZnO nanorods and P3HT based electrodes. The origin of superior photoelectrochemical properties of ZnO/P3HT photoanodes has been explained using carrier transport mechanism at semiconductor/electrolyte junction. The stability of ZnO NRs/P3HT photoanode has been demonstrated. (C) 2017 Elsevier B.V. All rights reserved.
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