Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 44, Pages 5974-5977Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc03072j
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Funding
- JSPS KAKENHI [JP15H05802, JP15H05993]
- Grants-in-Aid for Scientific Research [15H05802] Funding Source: KAKEN
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Cp*Co-III-catalyzed directed C-H trifluoromethylthiolation using N-trifluoromethylthiodibenzenesulfonimide as an electrophilic SCF3 source is described. 6-Arylpurines, an important structural motif in medicinal chemistry, and 2-phenylpyridines selectively afforded mono-trifluoromethylthiolated products in moderate to good yields using an inexpensive first-row transition metal catalyst.
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