Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 56, Issue 24, Pages 6783-6787Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201701094
Keywords
asymmetric catalysis; carbometalation; configurational stability; cyclopropanes; cyclopropenes
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Funding
- European Research Council under the Seventh Framework Program of the European Community (ERC) [338912]
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The highly diastereo- and enantioselective formation of polysubstituted cyclopropanes was easily achieved through the asymmetric copper-catalyzed carbomagnesiation reaction of nonfunctionalized cyclopropene derivatives. The carbometalated species generated in situ readily undergo C-C and C-X bond-forming reactions with various electrophiles with complete retention of configuration.
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