Journal
RSC ADVANCES
Volume 7, Issue 46, Pages 28723-28732Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ra05565j
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Funding
- Ministry of Education, Science and Technology [NRF-2014R1A2A1A11051794, NRF-2016M3D3A1A01913239]
- Nine Bridges Program Research Fund of UNIST (Ulsan National Institute of Science Technology) [1.170051.01]
- National Research Foundation of Korea [2014R1A2A1A11051794] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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A sulfonate-based chemosensor 1 was designed and synthesized for sensing various analytes: Cu2+, Fe2+/3+ and Al3+. Sensor 1 showed a high selectivity and sensitivity for the analytes in a near-perfect aqueous medium. Cu2+ and Fe2+/(3+) could be monitored by fluorescence quenching of 1. It had sufficiently low detection limits (1.25 mu M for Cu2+ and 3.96 mu M for Fe3+), which were below the recommended levels of the World Health Organization for Cu2+ (31.5 mu M) and the Environmental Protection Agency for Fe3+ (5.37 mu M). 1 showed the high preferential selectivity for Cu2+ and Fe3+ in the presence of competitive metal ions without any interference. Importantly, pyrophosphate could be used to distinguish Fe3+ from Cu2+. In addition, this sensor could monitor Al3+ through fluorescence emission change. Moreover, 1 was successfully applied to quantify and image Al3+ in water samples and living cells. Based on photophysical studies and theoretical calculations, the sensing mechanisms of 1 for Cu2+ and Al3+ were explained, respectively.
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