4.6 Article

A fluorescent chemosensor for Sn2+ and Cu2+ based on a carbazole-containing diarylethene

Journal

RSC ADVANCES
Volume 7, Issue 16, Pages 9833-9839

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra27339d

Keywords

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Funding

  1. National Natural Science Foundation of China [21363009, 21362013, 51373072]
  2. Science Funds of Natural Science Foundation of Jiangxi Province [20142BAB203005, 20132BAB203005]
  3. Young Scientist Training Program of the Jiangxi Province [20153BCB23008]
  4. JXSTNU Sci-Tech innovation team [2015CXTD002]
  5. Project of the Science Funds of Jiangxi Education Office [GJJ160774]

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A novel diarylethene with a carbazole moiety was developed for the highly selective and sensitive detection of Sn2+ and Cu2+ in methanol. Its fluorescence was enhanced with a 76 nm blue shift and selective fluorescence quenching occurred upon the addition of Sn2+ and Cu2+, respectively, over a wide range of tested cations. The compound formed complexes with Sn2+ and Cu2+ in a 1 : 1 stoichiometry and has the detection limits of 1.9 mu M and 1.2 mu M, respectively. Moreover, the compound can be applied to detect Sn2+ and Cu2+ in natural water samples with high accuracy.

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