Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 46, Pages 6195-6198Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc02400b
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Funding
- Thousand Talents Program'' of China
- National Natural Science Foundation of China [21101170, 21573139]
- Fundamental Research Funds for the Central Universities
- Research Funds of Renmin University of China
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Cobalt corroles with different acid/base pendants L-Br-Co L-COOH-Co L-PO(OH)2-Co and L-CH2PO(OH)2-Co(L=5,15-bis-(pentafluorophenyl)-10-(4-dibenzofuran) corrole) were synthesized and examined as catalysts for oxygen and hydrogen evolution from neutral aqueous solutions. Cobalt corroles with phosphonic acid pendants showed improved activities in both processes highlighting the importance of the secondary coordination sphere in catalyst design.
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