4.6 Article

Mercaptooxazole-phenazine based blue fluorescent sensor for the ultra-sensitive detection of mercury(II) ions in aqueous solution

Journal

RSC ADVANCES
Volume 7, Issue 75, Pages 47547-47551

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ra07992c

Keywords

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Funding

  1. National Natural Science Foundation of China (NSFC) [21662031, 21661028, 21574104, 21262032]
  2. Natural Science Foundation of Gansu Province [1506RJZA273]
  3. Program for Changjiang Scholars and Innovative Research Team in University of Ministry of Education of China [IRT 15R56]

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Herein, a mercury(II) ion fluorescent sensor (Z-3) with high sensitivity and immediate response is designed and synthesized. The sensor uses the phenazine group as a luminophore and sulfhydryl as a recognition moiety. The sensor is easily synthesized and it exhibits a remarkable blue shift with Hg2+. Correspondingly, its fluorescence color changes from yellow to blue. In addition, the low naked eye detection limit (10(-5)) of the sensor allows the identification of concentration limits. Moreover, the sensor could detect mercury(II) ions over a wide pH range (from 2 to 8), which indicates that the detection can be carried out in aqueous systems. In addition, test strips are fabricated, which could act as a convenient pathway for the recognition of Hg2+.

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