Journal
CHEMISTRY OF MATERIALS
Volume 29, Issue 11, Pages 4885-4893Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.chemmater.7b00857
Keywords
-
Funding
- Alexander von Humboldt Fellowship
- Marie Curie Fellowship (FP7-PEOPLE-IIF TANOGAPPs) [326385]
- National Natural Science Foundation of China [51673039]
- Shanghai Pujiang Talent Program [16PJ1400300]
- Fundamental Research Funds for the Central Universities [16D110618]
- Sino-German Center for Research Promotion [GZ879]
- EPSRC CDT Capital Grant [EP/K035746/1]
- Engineering and Physical Sciences Research Council [EP/K03927X/1] Funding Source: researchfish
- EPSRC [EP/K03927X/1] Funding Source: UKRI
Ask authors/readers for more resources
The design and synthesis of novel microporous. materials have received tremendous attention in both CO2 storage and sequestration (CSS) and electrochemical energy storage (EES). We report molecular design and synthesis of conjugated :microporous polycarbazole networks as new precursors for nitrogen-enriched porous carbons. As-prepared porous carbons exhibit a high nitrogen content (6.1 wt %), ulttamicropore size (0.7-1 nm), and large surface area (1280 m(3) g(-1)). As a result, these novel nitrogen-enriched carbons show highly efficient, and reversible CO2 capture (can store 20.4 wt % at I. bar and 11.1 wt % at 0:15 bar and at 273 K, while maintaining 100% CO2 uptake capacity after five cycles). Moreover, they can be applied as electrodes and enable high-performance EES devices with a fast charge/discharge rate (8 s), high electrochemical capacity (558 F g(-1)), and good cycle ability (retain 95% capacity after 1000 cycles).
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available