4.7 Article

3,4-Alkadienyl ketones via the palladium-catalyzed decarboxylative allenylation of 3-oxocarboxylic acids

Journal

CHEMICAL COMMUNICATIONS
Volume 53, Issue 44, Pages 6037-6040

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc02050c

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Funding

  1. National Natural Science Foundation of China [21232006]
  2. National Basic Research Program [2015CB856600]

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In this communication, we report a palladium-catalyzed decarboxylative allenylation of benzyl carbonates and tert-butyl carbonates of 2,3-allenols with 3-oxocarboxylic acids. The reaction provides a new and straightforward approach to 3,4-dienyl ketones under mild conditions.

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