Journal
RSC ADVANCES
Volume 7, Issue 1, Pages 128-131Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra25494b
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Funding
- China Scholarship Council
- Queen Mary University of London
- EU FP7 (Marie Curie-CIG-Grant) [303535]
- EPSRC [EP/K004484/1]
- National Science Foundation of China [61574095]
- Engineering and Physical Sciences Research Council [EP/K004484/1] Funding Source: researchfish
- EPSRC [EP/K004484/1] Funding Source: UKRI
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Erbium complexes with a fluorinated organic core shell linked to a hydrogen-containing shell, have been synthesized using the click reaction between erbium(III) bis(perfluoro-4-azidophenyl) phosphinate and a series of alkynes. The erbium 1.5 mu m emission lifetimes in the hydrogen-containing erbium complexes exceed 140 ms, the longest ever reported in hydrogenated organic erbium systems. The visible sensitisation for erbium emission indicates a successful strategy that broadens the usage of nonfluorinated chromophores in organic erbium systems and allows more choices for ligand functionalization with exceptional efficiency for erbium emission.
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