4.6 Article

Realization of uniaxially strained, rolled-up monolayer CVD graphene on a Si platform via heteroepitaxial InGaAs/GaAs bilayers

Journal

RSC ADVANCES
Volume 7, Issue 24, Pages 14481-14486

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra28482e

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Funding

  1. National Natural Science Foundation of China [61474008]
  2. Program for New Century Excellent Talents in University [NCET-13-0686]
  3. International Science & Technology Cooperation Program of China [2011DFR11010]
  4. 111 Project [B07005]

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III-V semiconductor/graphene tubular structures with diameters of 4.5-5.4 mu m have been fabricated on a silicon platform by rolling up monolayer CVD graphene together with heteroepitaxial InGaAs/GaAs bilayers. Scanning electron microscopy (SEM) reveals that transferred graphene adheres to the wall of the Si-based InGaAs/GaAs microtube. Micro-Raman spectroscopy measurements show remarkable redshifts of the G and 2D bands of graphene after planar graphene totally rolls up, reflecting that rolled-up graphene is under uniaxial tensile strain and the strain originates from the rolled-up InGaAs/GaAs microtube. We also fabricated GaAs-based III-V semiconductor/graphene tubular structures with diameters of 3.7 and 4.7 mu m, respectively, thus finding an approach to graphene strain engineering (i.e., the Raman redshift and tensile strain of rolled-up graphene increase with the decrement of microtube diameter). Obviously, assembling strained graphene with III-V semiconductors in rolled-up form on a Si platform will bring about a variety of Si-based electronic and optical applications in the future.

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