4.8 Article

Synthetic Melanin E-Ink

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 9, Issue 19, Pages 16553-16560

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsami.7b03890

Keywords

synthetic melanin; polydopainine; electronic ink; fluorescence display; nanoscale resolution

Funding

  1. State Key Laboratory of Polymer Materials Engineering, Sichuan University [sklpme2016-3-03]
  2. National Natural Science Foundation of China [21274131, 51273178, 51203139, 51303158]
  3. Natural Science Foundation of Zhejiang Province [LY15E030005]
  4. Pennsylvania State University

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Extensive efforts have been devoted to the development of surfactant free electronic ink (E-ink) with excellent display resolution for high-definition resolution display. Herein, we report the use of polydopamine-based synthetic melanin, a class of functional nanoparticles with similar chemical compositions and physical properties to those of naturally occurring melanin, as a new E-ink material. It was found that such E-ink displays could achieve ultrahigh resolution (>10 000 ppi) and low power consumption (operation voltage of only 1 V) in aqueous solutions. Interestingly, simple oxidation of synthetic melanin nanoparticles enables the generation of intrinsic fluorescence, allowing further development of fluorescent E-ink displays with nanoscale resolution. We describe these bioinspired materials in an initial proof-of-concept study and propose that synthetic melanin nanoparticles will be suitable for electronic nanoinks with a potential wide range of applications in molecular patterning and fluorescence bioimaging.

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