Journal
RSC ADVANCES
Volume 7, Issue 16, Pages 9780-9789Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra28855c
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Funding
- CONACyT [255819]
- PRODEP-SEP [DSA/103.5/16/10288]
- Royal Society (UK)
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An air-stable phosphinito palladium(II) complex (Ph1-Phoxide) has been found to be an efficient catalyst in the formation of C-C bonds. The coupling of terminal alkynes formed gem-1,3-enynes as the only reaction products. Aromatic alkynes can be synthesized from the coupling of terminal alkynes and haloaromatic compounds (Sonogashira coupling). The phosphinito palladium(II) complex also catalyses the coupling between acyl chlorides and terminal alkynes (Sonogashira coupling), furnishing ynones in excellent yields.
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