Journal
RSC ADVANCES
Volume 7, Issue 1, Pages 266-274Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra24786e
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- Universidad de Buenos Aires
- Conicet
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Radical initiation for the perfluoroalkylation reaction of amino(hetero) aromatics has been accomplished employing the complex [(TMEDA) I.I-3] and visible light. This methodology circumvents the use of metal(organo) catalysts and biologically-relevant substrates are easily substituted with RF moieties employing a mild and environmentally benign radical strategy starting from readily-available perfluoroalkyl iodides RFI.
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