Journal
RSC ADVANCES
Volume 7, Issue 56, Pages 35528-35536Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ra06083a
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Funding
- National Natural Science Foundation of China [21372147]
- Undergraduate Innovative Research Training Program of Shandong Normal University [201610445067]
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Herein, three novel cone thiacalix[4] pseudocrown receptors 1-3, bearing anthraquinone and triazole functions as well as different side arms, were successfully synthesized via a double click reaction as the key step. Their recognition properties have been fully evaluated using optical, electrochemical, and theoretical methods. Receptor 1 features high selectivity for Pb2+, whereas receptor 2 can optically recognize Zn2+ in the presence of Cd2+. This difference of binding specificity to metal ions may be ascribed to the remote tuning effect from the side arms connected to the lower rim of thiacalix[4] arene that realizes the accommodation of binding specificity. Moreover, the plausible coordination modes have been presented.
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