4.6 Article

Deep eutectic solvents as performance additives in biphasic reactions

Journal

RSC ADVANCES
Volume 7, Issue 64, Pages 40367-40370

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ra06755k

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Funding

  1. National Natural Science Foundation of China [31471690, 21406076]
  2. Science and Technology Planning project of Guangdong province [2014B020204003, 2015B020231006]

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Deep eutectic solvents act as surfactants in biphasic (hydrophobic/aqueous) reaction mixtures enabling higher interfacial surface areas at lower mechanical stress as compared to simple emulsions. Exploiting this effect the rate of a chemoenzymatic epoxidation reaction was increased more than six-fold.

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