Journal
RSC ADVANCES
Volume 7, Issue 1, Pages 408-414Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra25123d
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Funding
- National Natural Science Foundation of China [21502136, 21571137]
- Higher Educational Science and Technology Program of Shandong Province [J15LC18]
- Promotive Research Fund for Excellent Young and Middle-aged Scientists of Shandong Provine [BS2014CL035]
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Construction of porous organic polymers (POPs) as metal-free heterogeneous organic photocatalysts for highly efficient catalytic organic transformations using visible light remains a key challenge. Herein, we report the bottom-up strategy to facilely synthesize two Eosin Y dye-based POP frameworks (EY-POPs) for highly efficient heterogeneous organic-photocatalysis. Owing to the high BET surface area and the built-in character of the covalently linked catalytic sites of EY-POPs, these photoactive polymers show excellent catalytic activity in photocatalyzing the aza-Henry reaction. The superior utility of the EY-POP-1 polymer in catalysis was demonstrated by the broad scope of the reactants and the high yield of the reaction products. Moreover, the EY-POP-1 polymer shows robust recycling capability with good retention of photoactivity over at least twelve cycles without any significant loss of the catalytic activity (94-98% yield).
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